Diffuse Emission of CO2 from Showa-Shinzan, Hokkaido, Japan: A Sign of Volcanic Dome Degassing   总被引：1，自引：0，他引：1  

Pedro A. Hernández  Kenji Notsu  Hiromu Okada  Toshiya Mori  Masanori Sato  Francisco Barahona  Nemesio M. Pérez 《Pure and Applied Geophysics》2006,163(4):869-881

Two soil CO₂ efflux surveys were carried out in September 1999 and June 2002 to study the spatial distribution of diffuse CO₂ degassing and estimate the total CO₂ output from Showa-Shinzan volcanic dome, Japan. Seventy-six and 81 measurements of CO₂ efflux were performed in 1999 and 2002, respectively, covering most of Showa-Shinzan volcano. Soil CO₂ efflux data showed a wide range of values up to 552 g m^-2 d^-1. Carbon isotope signatures of the soil CO₂ ranged from -0.9‰ to -30.9‰, suggesting a mixing between different carbon reservoirs. Most of the study area showed CO₂ efflux background values during the 1999 and 2002 surveys (B = 8.2 and 4.4 g m^-2 d^-1, respectively). The spatial distribution of CO₂ efflux anomalies for both surveys showed a good correlation with the soil temperature, indicating a similar origin for the extensive soil degassing generated by condensation processes and fluids discharged by the fumarolic system of Showa-Shinzan. The total diffuse CO₂ output of Showa-Shinzan was estimated to be about 14.0–15.6 t d^-1 of CO₂ for an area of 0.53 km².  相似文献   

爆裂法作为快速测定流体包裹体中二氧化碳（和其它气体）含量的手段及其在勘探中的使用：以中国山东和河北省金矿为例   总被引：1，自引：0，他引：1  

Kingsley Burlinson 《岩石学报》2007,23(1):65-71

The acoustic decrepitation method heats a small monomineralic sample and counts pressure impulses as the inclusions burst when they develop high internal pressures.For aqueous fluids,the decrepitation temperature is correlated with the homogenisation temperature,but gas rich fluids give a distinct and characteristic low temperature decrepitation peak which can be used to recognize gas rich fluid inclusions.This information is useful in exploration for Au deposits,which are frequently associated with CO_2 rich and sometimes CH_4 rich fluids. This distinctive decrepitation occurs because the CO_2 rich inclusion fluids expand according to the gas law and develop internal pressures high enough to burst the host mineral grain at temperatures well below their homogenisation temperatures.In contrast,aqueous fluids condense to a liquid and vapour phase during post-entrapment cooling.Upon subsequent heating their internal pressures do not increase significantly until after homogenisation to a single phase occurs and hence they do not decrepitate"prematurely"as gas rich inclusions do. This behaviour is usually regarded as an annoyance in conventional microthermometric homogenisation studies,but can readily be used as an exploration aid to find mineralisation deposited from such gas rich fluids.Decrepitation results on samples from Cowra Ck, NSW,Australia,which have also been microthermometrically measured for CO_2 content,show that amounts of less than 5 mole % CO_2 are easily distinguished by decrepitation and amounts as low as 1 mole % CO_2 may be determinable. Examples of the use of acoustic decrepitation in the study of 6 gold mines in the Shandong and Hebei provinces of China are discussed.  相似文献   

Tilt corrections over complex terrain and their implication for CO<Subscript>2</Subscript> transport     

Jielun Sun 《Boundary-Layer Meteorology》2007,124(2):143-159

Observational data from sonic anemometers are commonly rotated from sonic to streamline coordinates, a procedure that is called tilt correction. Tilt corrections are often used to post-process air velocity data collected from sonic anemometers to allow objective interpretation of air flow data relative to the Earth. Since streamline coordinates depend on dynamical characteristics of the flow, the tilt correction depends not only on temporal and spatial variations of the flow, but also on local circulations. We found that ensemble- averaged slope flows are approximately parallel to the terrain slope close to the ground within the canopy layer, but not above, due to the influence of the diurnal variation of local vertical circulations. As a result, the diurnal variation of the observed vertical velocity in streamline coordinates at 21.5 m above the ground over 11-m tall forest canopies can be opposite to that calculated from the continuity equation. To estimate CO₂ transport over sloping terrain, a workable reference coordinate system is needed such that multiple sonic anemometers have a common reference relative to the Earth. Streamline coordinate systems can be the choice of the common reference coordinate system only if flow, at least ensemble-averaged flow, is parallel to terrain slopes. The choice of the reference coordinate system and its implication in investigation of CO₂ transport are discussed. The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

The Atmospheric Oxidation of the HS Radical: Reaction with NO2     

Stella M. Resende 《Journal of Atmospheric Chemistry》2007,56(1):21-32

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.  相似文献   

Silicon Isotope Geochemistry of Micro—Fine Disseminated Gold Deposits in SW Guizhou and NW Guangxi,China     

刘显凡  倪师军等 《中国地球化学学报》1998,17(3):249-257

Quartz was studied with respect to its silicon isotopic composition and cathodoluminescence in micro-fine disseminated gold deposits in SW Guizhou and NW Guangxi.The results showed that quartz in wall rocks.ores and that in association with hydrothermal silicification are distinctive in silicon isotopes and cathodoluminescence characters.Quartz in association with primary silicification is non-luminescent while that in wall rocks and associated with secondary silicification exhibits striking luminescence.Based on the dynamic fractionation of silicon isotopes,it is suggested that the mineralization was accompanied by rapid transport of aprimary siliceous fluid along the major deep fault system into subordinate faults before ore components deposited in favorable strata via penetration and metasomatism.Therefore,a deep origin is implicit for gold deposits of this type.  相似文献   

岩溶发育对温室气体CO2的调节能力研究     

王青海  田瑛 《地质灾害与环境保护》1998,9(1):49-52,56

温室效应是当今世界上许多国家及其政府关注的重要问题之一。从地质角度研究全球最大碳库－－碳酸盐岩在其岩溶发育过程中对温室气体ＣＯ２的调节能力,从而为更全面,定量地考察温室气体ＣＯ２循环提供新思路及依据。  相似文献   

Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles     

Roy M. Harrison  Gareth M. Collins 《Journal of Atmospheric Chemistry》1998,30(3):397-406

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献   

The ocean as source or sink of reactive trace-gases     

H. W. Georgii  G. Gravenhorst 《Pure and Applied Geophysics》1977,115(3):503-511

Summary After a brief review on recent experimental work on the uptake resp release of SO₂ and NH₃ by the ocean, new results on the distribution of these reactive trace-gases in the marine atmosphere are presented. In the case of SO₂ there is no doubt that the ocean acts as a sink. In the case of NH₃ new observations and calculations show that under certain conditions the ocean may be a NH₃ source.  相似文献   

二氧化氯控制欧洲鳗细菌性疾病     

何义进  邢华  熊家娟 《广东海洋大学学报》2000,20(1)

以二氧化氯作为一种新型的消毒剂和杀菌剂 ,以传统含氯制剂 (如漂白粉、二氯异氰尿酸钠、三氯异氰尿酸 )作为对照 ,比较其在治疗欧洲鳗细菌性疾病及改善养殖水质方面的显著特性 ,其作用活性与环境 (如 p H、温度、氨及有机物 )因子的关系。结果表明 ,二氧化氯 (Cl O2 )对爱德华氏菌、嗜水气单胞菌和柱状屈挠杆菌有很好的杀灭效果 ,能迅速治愈欧洲鳗的赤鳍病和肝肾病 ,且能有效改善养殖水体 ,水中生化需氧量比对照组下降 10 %～ 30 % ,化学耗氧量下降 5% ,溶氧量提高 8%～ 10 %。当二氧化氯体积分数为 8m L/m3时 ,其杀菌率均高达 90 %以上 ,为氯制剂的 1.8倍 ,且活性不受环境因子的影响  相似文献   

Parameter analysis for gate metal—oxide—semiconductor structures of ion-implanted 4H silicon carbide metal—semiconductor field-effect transistors     

王守国  张义门  张玉明 《海洋学报(英文版)》2010,29(9)

From the theoretical analysis of the thermionic emission model of current--voltage characteristics, this paper extracts the parameters for the gate Schottky contact of two ion-implanted 4H-SiC metal--semiconductor field-effect transistors (sample A and sample B for three and four times multiple ion-implantation channel region respectively) fabricated in the experiment, including the ideality factor, the series resistance, the zero-field barrier height, the interface oxide capacitance, the interface state density distribution, the neutral level of interface states and the fixed space charge density. The methods to improve the interface of the ion-implanted Schottky contact are given at last.  相似文献